Development of Photovoltaic Devices Based on Fullerene–Graphene Hybrids
DOI:
https://doi.org/10.64470/elene.2025.15Keywords:
Fullerene, Graphene Hybrid nanomaterials, Organic solar cells, Perovskite solar cells, Photovoltaic devices, Sustainable energyAbstract
The development of next-generation photovoltaic devices requires the integration of advanced nanomaterials with superior electrical, optical, and mechanical properties. Among such materials, fullerenes (C₆₀ and their derivatives such as PCBM) and graphene have attracted significant attention due to their complementary functionalities. Fullerenes act as efficient electron acceptors, facilitating charge separation in donor–acceptor systems. While graphene provides excellent electrical conductivity, high optical transparency, and mechanical flexibility, making it a promising alternative to conventional transparent electrodes such as indium tin oxide (ITO).
This paper reviews recent progress in the design and fabrication of fullerene–graphene hybrid photovoltaic devices. The typical device structure includes a flexible or rigid substrate, a graphene transparent electrode, a polymer–fullerene active layer, selective charge transport layers, and a metallic back contact. Experimental studies demonstrate that hybridization of fullerenes with graphene improves charge transport pathways, reduces series resistance, and enhances power conversion efficiency (PCE). Furthermore, fullerene–graphene composites contribute to device stability under prolonged illumination and thermal stress.
Overall, fullerene–graphene hybrid materials represent a promising strategy for the development of high-efficiency, cost-effective, and flexible solar cells. Their potential applications extend beyond traditional photovoltaics to include portable energy sources, building-integrated photovoltaics, and wearable electronic devices, contributing to the broader goal of sustainable energy technologies.
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Atajonov, M.: Development of technology for the development of highly efficient combinations of solar and thermoelectric generators. AIP Conf. Proc. 3045, 020011 (2024). https://doi.org/10.1063/5.0197733.
Atazhonov, M.O., Mamarasulov, Q., Gimaeva, L.M., and Suleimanov R.I. “Mathematical model of a photoelectric thermal electric energy converter under load”, Proc. SPIE 13662, Fourth International Conference on Digital Technologies, Optics, and Materials Science (DTIEE 2025), 136620O (5 June 2025); https://doi.org/10.1117/12.3072651.
Brabec, C. J., Dyakonov, V., Parisi, J., & Sariciftci, N. S. (2011). Organic photovoltaics: Concepts and realization. Springer. https://doi.org/10.1007/978-3-642-22263-5.
Castro, E., Murillo, J., Fernandez-Delgado, O., & Echegoyen, L. (2018). Progress in fullerene-based hybrid perovskite solar cells. Journal of Materials Chemistry C, 6(1), 263–276. https://doi.org/10.1039/C7TC04706K.
Chen, M., Yin, X., & Li, J. (2018). Hybrids of fullerenes and 2D nanomaterials: A new family of functional materials. Small, 14(19), 1702838. https://doi.org/10.1002/smll.201702838.
Forrest, S.R. “The path to ubiquitous and low-cost organic electronic appliances on plastic,” Nature, vol. 428, pp. 911–918, 2004.
Gatti, T., Menna, E., Meneghetti, M., Maggini, M., Petrozza, A., & Lamberti, F. (2017). The renaissance of fullerenes with perovskite solar cells. Nano Energy, 41, 84–100. https://doi.org/10.1016/j.nanoen.2017.08.038.
Green, M. A. (2006). Third generation photovoltaics: Advanced solar energy conversion. Springer. https://doi.org/10.1007/3-540-28556-7.
Heeger, A. J. (2014). 25th Anniversary Article: Bulk heterojunction solar cells: Understanding the mechanism of operation. Advanced Materials, 26(1), 10–28. https://doi.org/10.1002/adma.201304346.
Kasimakhunova, A.M, Atazhonov, M.O., Gizzatullina, A.A., Garifullina, G.I and Gimaeva, L.M. “Investigation of the possibility of creating a film photothermal converter”, Proc. SPIE 13662, Fourth International Conference on Digital Technologies, Optics, and Materials Science (DTIEE 2025), 1366212 (5 June 2025); https://doi.org/10.1117/12.3072647.
Mahmoudi, T., Wang, Y., Hahn, Y. B., & Kim, H. (2018). Graphene and its derivatives for solar cells application. Nano Energy, 47, 51–65. https://doi.org/10.1016/j.nanoen.2018.02.009.
Miao, J., Zhang, H., Zhang, J., & Wang, X. (2023). Flexible and stretchable transparent conductive graphene electrodes for optoelectronic devices. Carbon, 204, 1–20. https://doi.org/10.1016/j.carbon.2023.01.020.
Muchuweni, E., Singh, A., & Shumbula, P. (2021). Graphene-based materials in perovskite solar cells: A review. Advanced Energy and Sustainability Research, 2(4), 2100004. https://doi.org/10.1002/aesr.202100004.
Mustonen, P., Kaskela, A., Mattila, T., Susi, T., & Kauppinen, E. I. (2020). Large-area graphene transparent electrodes: Fabrication routes and applications. Micromachines, 11(5), 483. https://doi.org/10.3390/mi11050483.
Novoselov, K. S., & Geim, A. K. (2007). The rise of graphene. Nature Materials, 6(3), 183–191. https://doi.org/10.1038/nmat1849
Que, M., Li, J., Wang, Y., & Zhou, H. (2021). Carbon-based electrodes for perovskite solar cells. Materials Advances, 2(5), 1500–1517. https://doi.org/10.1039/D0MA00717K.
Sharma, A., Singh, P., & Kumar, A. (2022). Recent advances in bulk heterojunction solar cells: Materials, device architectures, and challenges. EPJ Applied Physics, 97(3), 30901. https://doi.org/10.1051/epjap/2022220087.
Sze, S. M., & Ng, K. K. (2007). Physics of semiconductor devices (3rd ed.). Wiley. https://doi.org/10.1002/0470068329.
Velasco Davoise, L., Reynaud, F., & Roussel, H. (2022). Application of graphene-related materials in organic photovoltaic devices. Materials, 15(2), 390. https://doi.org/10.3390/ma15020390.
Wadsworth, A., Moser, M., Marks, A., Little, M. S., Gasparini, N., Brabec, C. J., & McCulloch, I. (2020). The bulk heterojunction in organic photovoltaics: Morphology, scale, and material interfaces. Advanced Materials, 32(26), 2001763. https://doi.org/10.1002/adma.202001763.
Yang, T., Liu, J., Wang, Z., & Li, F. (2020). Fullerene/graphene composite electrodes for advanced photovoltaic devices. Solar Energy Materials and Solar Cells, 210, 110461. https://doi.org/10.1016/j.solmat.2020.110461.
Zhang, D., Wang, J., Zhao, X., & Chen, L. (2017). Fullerene–graphene hybrid materials for high performance solar cells. Journal of Materials Chemistry A, 5(38), 19997–20004. https://doi.org/10.1039/C7TA06583A.
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