Impact of Oxygen Concentration on High-Load PEMFC Efficiency: A Simulink-Based Study
DOI:
https://doi.org/10.64470/elene.2026.29Keywords:
Concentration Loss, High load operation, MATLAB-Simulink, Oxygen enrichment, PEMFCAbstract
Energy consumption and the utilization of sustainable energy sources are of great importance for the economic independence and environmental stability of nations. Turkey, as a country heavily dependent on energy imports, faces a critical need to develop domestic and renewable energy resources. The low carbon emissions and environmentally friendly nature of hydrogen have attracted significant attention within the scope of international agreements such as the Kyoto Protocol. Proton Exchange Membrane Fuel Cells (PEMFCs) stand out among clean energy technologies due to their low operating temperatures (60–80°C), high power density, and zero-emission potential. However, concentration losses occurring on the cathode side under high load conditions represent a significant problem that considerably reduces PEMFC efficiency and has not been sufficiently addressed in the literature.
This study investigates the effect of inlet air O₂ on PEMFC efficiency under different load conditions using a MATLAB-Simulink simulation model. The results demonstrate that increasing the oxygen concentration under 50% load conditions yields only a marginal efficiency improvement of approximately 3%. In contrast, under 90% load conditions, increasing the O₂ enrichment level from 21% to 100% improves efficiency by approximately 10%, and this gain can reach up to 15% with additional pressurization measures. This finding clearly demonstrates that increasing oxygen concentration provides a meaningful contribution only under high load conditions, while such intervention is unnecessary within the optimal load range. The results present a practical strategy for improving PEMFC efficiency in heavy-load applications such as intercontinental cargo ships and freight trains, and directly contribute to the literature on PEMFC systems operating under high load conditions.
Downloads
References
Ansari, S. A., Khalid, M., Kamal, K., Abdul Hussain Ratlamwala, T., Hussain, G., & Alkahtani, M. (2021). Modeling and Simulation of a Proton Exchange Membrane Fuel Cell Alongside a Waste Heat Recovery System Based on the Organic Rankine Cycle in MATLAB/SIMULINK Environment. Sustainability, 13(3), 1–21. https://doi.org/10.3390/su13031218
Baz, F. B., Elzohary, R. M., Osman, S., Marzouk, S. A., & Ahmed, M. (2024). A review of water management methods in proton exchange membrane fuel cells. Energy Conversion and Management, 302, 118150. https://doi.org/10.1016/j.enconman.2024.118150
Beni Hamed, S., & Ben Hamed, M. (2024). Modeling and Simulation of a Proton Exchange Membrane Fuel Cell Stacks in MATLAB/SIMULINK Under Conditions Variations. Green Energy and Technology, 255–266. https://doi.org/10.1007/978-981-97-6148-7_25
BP. (2022). Statistical Review of World Energy 2022. BP p.l.c. https://www.bp.com/content/dam/bp/business-sites/en/global/corporate/pdfs/energy-economics/statistical-review/bp-stats-review-2022-full-report.pdf
Dincer, I., & Acar, C. (2015). Review and evaluation of hydrogen production methods for better sustainability. International Journal of Hydrogen Energy, 40(34), 11094–11111. https://doi.org/10.1016/j.ijhydene.2014.12.035
Erkök, B., & Kütük, Y. (2023). Dependency On Imported Energy In Turkey: Input-Output Analysis. Marmara Üniversitesi İktisadi ve İdari Bilimler Dergisi, 1(45), 47–70. https://doi.org/10.14780/muiibd.1317197
Incer-Valverde, J., Korayem, A., Tsatsaronis, G., & Morosuk, T. (2023). “Colors” of hydrogen: Definitions and carbon intensity. Energy Conversion and Management, 291, 117294. https://doi.org/10.1016/j.enconman.2023.117294
Kusoglu, A., & Weber, A. Z. (2017). New Insights into Perfluorinated Sulfonic-Acid Ionomers. Chemical Reviews, 117(3), 987–1104. https://doi.org/10.1021/acs.chemrev.6b00159
Mann, R. F., Amphlett, J. C., Hooper, M. A. I., Jensen, H. M., Peppley, B. A., & Roberge, P. R. (2000). Development and application of a generalised steady-state electrochemical model for a PEM fuel cell. Journal of Power Sources, 86(1–2), 173–180. https://doi.org/10.1016/S0378-7753(99)00484-X
Mench, M. M. (2008). Fuel Cell Engines. Fuel Cell Engines, 1–515. https://doi.org/10.1002/9780470209769
Rohendi, D., Majlan, E. H., Mohamad, A. B., Daud, W. R. W., Kadhum, A. A. H., & Shyuan, L. K. (2015). Effects of temperature and backpressure on the performance degradation of MEA in PEMFC. International Journal of Hydrogen Energy, 40(34), 10960–10968. https://doi.org/10.1016/j.ijhydene.2015.06.161
Sherif, S. A., Barbir, F., & Veziroglu, T. N. (2005). Wind energy and the hydrogen economy—review of the technology. Solar Energy, 78(5), 647–660. https://doi.org/10.1016/j.solener.2005.01.002
Smith, P. J., Bennett, W. R., Jakupca, I. J., Gilligan, R. P., & Edwards, L. G. (2021). Effect of Reactant Pressure on Proton Exchange Membrane Fuel Cell Performance. NTRS - NASA Technical Reports Server. NTRS - NASA Technical Reports Server. https://ntrs.nasa.gov/citations/20205011192
Wang, Y., Chen, K. S., Mishler, J., Cho, S. C., & Adroher, X. C. (2011). A review of polymer electrolyte membrane fuel cells: Technology, applications, and needs on fundamental research. Applied Energy, 88(4), 981–1007. https://doi.org/10.1016/j.apenergy.2010.09.030
Wang, Z. B., Zuo, P. J., Chu, Y. Y., Shao, Y. Y., & Yin, G. P. (2009). Durability studies on performance degradation of Pt/C catalysts of proton exchange membrane fuel cell. International Journal of Hydrogen Energy, 34(10), 4387–4394. https://doi.org/10.1016/j.ijhydene.2009.03.045
Weber, A. Z., & Newman, J. (2004). Modeling Transport in Polymer-Electrolyte Fuel Cells. Chemical Reviews, 10(104), 4679–4726. https://doi.org/10.1021/cr020729l
Xia, B., Guo, P., Wei, X., & Zong, H. (2023). Reaction Gas Pressure, Temperature, and Membrane Water Content Modulate Electrochemical Process of a PEMFC: A Simulation Study. Advances in Materials Science and Engineering, 2023(1), 1346872. https://doi.org/10.1155/2023/1346872
Zhang, J., Song, C., Zhang, J., Baker, R., & Zhang, L. (2013). Understanding the effects of backpressure on PEM fuel cell reactions and performance. Journal of Electroanalytical Chemistry, (688), 130–136.
Zhou, X., Fan, L., Chan, S. H., & Tu, Z. (2026). From Performance Boost to Degradation Mechanism: How Oxygen-Enriched Cathode Operation Enhances Durability in PEMFCs. Advanced Sustainable Systems, 10(3), e01721. https://doi.org/10.1002/adsu.202501721
Downloads
Published
Data Availability Statement
No datasets were generated or analyzed during the current study.
Issue
Section
License
Copyright (c) 2025 Cemaleddin Uğuz, Mehmet Akif Şahman

This work is licensed under a Creative Commons Attribution 4.0 International License.
Authors retain copyright of their work and grant the journal the right to publish it under the Creative Commons Attribution 4.0 International License (CC BY 4.0). This allows for maximum dissemination and reuse with appropriate citation.
ORCID 